Cyclopalladated ferrocenylimines catalyzed Suzuki cross-coupling reaction of aryl iodides,bromides with 3-thienylboronic acid was carried out in DMF at 80 ℃ in the pr.
5%的二茂铁亚胺环钯化合物在DMF/K3PO4/80℃条件下,能够有效地催化3-噻吩硼酸同芳基碘和芳基溴的Suzuki反应,方便地合成系列3-芳基噻吩衍生物。
Cyclopalladated ferrocenylimine catalyzed Suzuki cross-coupling reactions toafford ortho-substituted biarylsThe application of cyclopalladated ferrocenylimines 1 and 2 in the coupling of arylhalides with 2-methoxy-1-naphthylboronic for the synthesis of ortho-substitutedbiaryls was studied.
一、环钯化二茂铁亚胺-三苯基膦配合物催化Suzuki偶联反应生成带邻位取代基的二芳基化合物的研究研究了二茂铁亚胺环钯化合物1和2在芳基卤代物与带有邻位取代基的2-甲氧基-1-萘基硼酸偶联反应中的催化性能，重点考察了催化剂、碱、溶剂以及底物对此偶联反应的影响，发现在无惰气保护情况下，以CsF为碱，在二氧六环中回流，环钯化二茂铁亚胺—三苯基膦配合物2以0。
Studies on Cyclopalladated Ferrocenylimines and Au(Ⅰ) Catalyzed Suzuki Cross-coupling Reaction;
二茂铁亚胺环钯化合物和Au（Ⅰ）催化的Suzuki偶联反应研究
Cyclopalladated Ferrocenylimines Complexes: Synthesis, Characterization and Application in C-C and C-N Coupling Reactions;
二茂铁亚胺环钯化合物的合成、表征及其催化的C-C和C-N偶联反应
Synthesis and Application of Heteroannular Cyclopalladated Ferrocenylimines Involving Heterocycle;
含杂环二茂铁亚胺异环环钯化合物的合成及应用
Studies on the Suzuki Coupling Catalyzed by Phosphine Adducts of Cyclopalladated Ferrocenylimines;
环钯化二茂铁亚胺一膦配合物催化的Suzuki反应研究
Synthesis of Chiral Cyclopalladated Ferrocenylimines and α-ferrocenyl-α-aminophosphine Oxides and Their Application in Asymmetric Catalysis;
手性二茂铁亚胺的环钯化合物和α-胺基膦氧化物的合成及在不对称催化中的应用
Application Studty of Cyclometallated Ferrocenylimines;
二茂铁亚胺环金属化合物的应用研究
Synthesis and Application of Palladium(Ⅱ), Mercury(Ⅱ) Complexes with Ferrocenylimines and 2-arylnaphthoxazoles;
二茂铁亚胺及2-芳基萘骈噁唑钯、汞化合物的合成与应用
Synthesis of Tertiary Ferrocenylamines and the Mechanistic Studies of Their Ortho-mercuration, Cyclopalladation;
二茂铁叔胺衍生物的合成及其邻位汞化、环钯化反应的机理研究
Studies on the Heck Reaction Catalyzed by Palladacycle Complexes Anchored on Active Carbon;
活性炭负载二茂铁环钯化合物催化Heck反应研究
Studies on the Syntheses, Properties of the Five-membered Heterocyclic Compounds Containing Nitrogen and Palladium Complex of the Chiral Ferrocenyldiamine;
水杨基含氮五元杂环化合物与手性二茂铁二胺钯络合物的合成与研究
Regioselective Cyclopalladation of 1'-benzoyl-1-[(arylimino)phenylmethyl]ferrocene;
1’-苯甲酰基-1-[（芳亚胺基）苯甲基]二茂铁区域选择性的环钯化反应
Synthesis, Characterization and Catalytic Performance of Ferrocenylimine Molybdenum (VI) Complexes for Epoxidation
二茂铁基亚胺钼（VI）配合物的合成、表征及催化环氧化性能研究
Studies on the Heck Reaction and Aza-Claisen Rearrangement Catalyzed by Ferrocenyl Palladic Compounds;
二茂铁钯化合物催化Heck、Claisen重排反应研究
Synthesis and characterization of diferrocenyl acidamide
双二茂铁基酰胺化合物的合成与表征
Synthesis and Catalytic Activity of Bis(ferrocenylcarbaldimine) Dioxomolybdenum(VI) Complex
双二茂铁基醛亚胺钼(VI)配合物的合成及催化性能
Synthesis and Characterization of Schiff-bases Containing Ferrocenyl and Platinum or Palladium Complexes;
含二茂铁基席夫碱及铂钯配合物的合成和表征
Synthetic Methods Studies on Ferrocenylketimines and Synthesis of Tertiary Ferrocenylamines;
乙酰基二茂铁亚胺合成方法学及苯甲酰二茂铁苄基叔胺的合成
Synthesis of the Thiazoles Substituted by Ferrocene;
二茂铁取代的噻唑类杂环化合物的合成