A free radical seeded emulsion polymerization model with the monomer partition was presented.
伴有水解缩合反应的自由基种子乳液聚合反应是制备有机-无机杂化乳胶粒的一种新方法,水解缩合反应和自由基聚合这两种反应在乳液体系中的动力学耦合过程决定了聚合产物的微结构和应用性质。
Tricopolymer macromolecular modifier, MAA-BA-AN,was synthesized by radical polymerization from methacrylic acid(MAA),butyl acrylate(BA) and acrylic nitrile(AN).
以甲基丙烯酸(MAA),丙烯酸丁酯(BA)和丙烯腈(AN)为单体,通过自由基溶液聚合法合成了MAA-BA-AN三元共聚物大分子表面改性剂,其结构和性质经1HNMR,13C NMR,FT-IR,GPC,TGA及DSC等表征。
In this work,a new macromolecular modifier butyl acrylate-methyl methacrylate-vinyltriethoxysilane(BA-MMA-VTES tercopolymer)was synthesized via radical polymerization under optimum conditions adopting BPO and DCP as initiators.
针对弱极性天然/丁苯橡胶复合体系,从分子设计的角度出发,选择乙烯基三乙氧基硅氧烷(VTES)、丙烯酸丁酯(BA)、甲基丙烯酸甲酯(MMA)为单体,通过自由基溶液聚合并优化了反应条件:在85℃和115℃分别加入两种不同量的引发剂BPO和DCP,均保温反应2h,合成了三元共聚物BA-MMA-VTES大分子表面改性剂,用于纳米碳化硅、氮化硅陶瓷粉体的表面改性。
free radical initiated emulsion polymerization
自由基引发乳液聚合
Emulsion and Miniemulsion Polymerization of MMA Via Reversible Addition-Fragmentation Transfer (RAFT) in the Presence of Solubilizer;
增溶剂存在下甲基丙烯酸甲酯乳液和细乳液RAFT活性自由基聚合
Submicro-capsule Preparation Via Interfacially Confined Living Free Radical Miniemulsion Polymerization;
界面活性自由基细乳液聚合制备亚微米胶囊
The Reasearch of Ratrp of Styrene in Microemulsion;
苯乙烯反向原子转移自由基微乳液聚合的研究
Reversible Addition-Fragmentation Transfer (RAFT) Living Polymerization of Styrene Miniemulsion in the Presence of Solubilizer;
增溶剂存在下苯乙烯细乳液RAFT活性自由基聚合
Controlled/Living Radical Polymerization in Emulsion
乳液体系中“活性”/控制自由基聚合研究进展
PLASMA-INITIATED EMULSION POLYMERIZATION OF (2-ETHTYL HEXYL) ACRYLATE
等离子体引发丙烯酸(2-乙基)已酯乳液聚合
Living Radical Polymerization with Iodide Formed in Situ;
原位生成碘化物引发活性自由基聚合
Atom Transfer Radical Emulsion Polymerization and Synthesis of New Type Block Copolymers;
原子转移自由基乳液聚合及新型嵌段共聚物的合成
Free Radical Polymerization Initiated by Initiator Containing Xanthone Structure;
含氧杂蒽酮结构引发剂引发自由基聚合研究
Preparation of PMMA-b-PSt by initiation of macroinitiator-containing fragments coming from Bixan-initiated polymerization of methyl methacrylate
含Bixan残基的大分子引发剂引发自由基聚合制备嵌段共聚物
Ultrasonic Induced Emulsion and Microemulsion Polymerization of Methyl Methacrylate and Preparation of Composites with Inorganic Nanoparticles;
甲基丙烯酸甲酯乳液和微乳液超声辐照引发聚合以及与无机纳米粒子复合的研究
Study of lauryl methacrylate emulsion polymerization by γ-rays irradiation and its oil absorption performances
γ射线引发甲基丙烯酸十二酯乳液聚合及其吸油性能的研究
Study on Thermal Initiation in Stable Free Radical Polymerization of Styrene;
苯乙烯稳定自由基聚合热引发作用的研究
The Atom Transfer Radical Polymerization and Degenerative Transfer Polymerization Initiated by Initiator Formed in Situ
原位合成引发剂引发原子转移自由基及衰减链转移同步聚合
Reversed Atom Transfer Radical Polymerization of Styrenein the Initiator of AIBN/CuCl_2/bpy;
反原子转移自由基聚合的研究——AIBN/CuCl_2/bpy引发St聚合
Controlled/living Radical Polymerization in Presence of NBS as an Iniferter and an ATRP Initiator;
NBS作引发转移终止剂及ATRP引发剂的可控/活性自由基聚合
BP/THF initiation system initiated norbornene with maleic anhydride visible radical copolymerization
BP/THF引发体系引发降冰片烯与马来酸酐可见光自由基共聚合