The mechanism of photoreaction in solvent with strong nucleophilicity was SET(single electron transfer) and cyclized products could be obtained in high yield,however,for the photoreaction in solvent with weak nucleophilicity,mechanisms of SET and hydrogen atom abstraction existed together.
在强亲核性溶剂中反应以单电子转移机制进行,并以很高的产率得到环化物;在弱亲核性溶剂中Norrish TypeⅡ和单电子转移机制同时存在。
Excited-state N-(ω-trimethylsilylmethyl)polypeptidephthalimides could carry out SET(single electron transfer) reaction by photoinduction to produce 1,ω-biradical.
在光诱导下,激发态的氮-(ω-三甲基硅甲基)聚肽链邻苯二甲酰胺经单电子转移形成1,ω-双自由基,其耦合形成聚肽环化物。
A possible mechanism involving thermoinduced single electron transfer of al lylic amines and radical cycloaddition was proposed.
该反应可能经过了热引发的烯丙胺的单电子转移过程 ,产生烯丙基自由基 ,并进一步与C6 0 加成及环化 。
Measurement of single-electron transfer cross sections in collision of C~(3+) with neon at intermediate velocity;
中速C~(3+)与Ne原子靶相互作用过程中单电子转移绝对截面的测量
Measurement of single-electron transfer cross sections in collisions of C~(3+) with He,Ne,Ar atoms at low to intermediate velocity;
中低速C~(3+)与He,Ne,Ar原子相互作用过程中单电子转移绝对截面的测量