Quantum Chemical Study on the Cycloaddition Reaction of Dichlorocarbene and Benzene;
二氯卡宾与苯环加成反应机理的量化研究
Studies on the Reaction and Mechanism of Tetrachloromethane with Magnesium──A Novel Method for the Generation of Dichlorocarbene;
四氯化碳与镁的反应及其反应机理的研究──产生二氯卡宾的新方法
Synthesized conditions of α-chlorocyclohexane carboxylic acid from dichlorocarbene and cyclohexanone were studied in the presence of phase-transfer catalyst TCMAC.
在相转移催化剂氯化三辛基甲铵(TCMAC)的存在下,二氯卡宾与环己酮反应制备α 氯环已烷羧酸,研究了该反应的合成条件对产率的影响,找到了最佳合成条件,产率可达73。