With 1, 10 - phenanthroline and 2,9 - dimethyl - 1, 10 - phenanthroline, a new bridge ligand 2,9- bis(2-imidazo[4,5 -f][1,10]phenanthroline) - 1,10- phenanthroline (BIPP) was synthesized and characterized by means of elemental analysis, mass spectrum, infrared spectrum and thermal analysis.
以邻菲咯啉和2,9-二甲基邻菲咯啉为原料,合成了新的桥联配体2,9-二(2-咪唑并[4,5-f]邻菲咯啉)邻菲咯啉。
In the dinuclear complexes with two dissimilar bridges, the highest occupied molecular orbitals (HOMO′S) of the bridging ligands interact with the magnetic orbitals of the metal ions according to the matching of symmetries.
如果两种桥联配体稳定同一磁轨道组合,则称它们以互补方式起作用;反铁磁偶合就会被加强。
The new oxalamide bridging ligands N,N′-bis(4-hydroxy-3-methoxy-benzyl)oxalamide(H4LB) was designed and synthesized.
设计合成一种新型对称的草酰胺桥联配体:N,N′-二(4-羟基-3-甲氧基苯甲基)草酰胺配体(H4LB)。
The new symmetrical rigid pyrazole-amide bridging ligands——3,5-bis[N-(2-hydroxy-3-methoxybenzoic)-carbamoyl] pyrazole(H5L)was synthesized in seven steps starting from o-vanillin,acetylacetone,hydrazine hydrate used as raw materials.
以邻香兰素、乙酰丙酮、水合肼等为原料,经7步反应合成了一种新型刚性对称吡唑、酰胺桥联配体,即标题化合物。
Synthesis、Structures and Properties of Dithiooxamide Bridging Ligands and Their Complexes;
二硫代草酰胺类桥联配体及其配合物的合成、结构及性质研究
Synthesis, Structures and Properties of Novel Supramolecular Coordination Polymers Generated from 5-Nitroisophthlate Ligand;
5-硝基间苯二甲酸桥联配体构筑的超分子配位聚合物的合成、结构及性能研究
Studies on the Syntheses and Crystal Structures of the Complexes Bridged by the Ligand of 4, 4'-Bipyridine;
4,4’-联吡啶桥联配合物的合成及其晶体结构研究
The Studies for the Synthesis, Crystal Structure and Magnetic Properties of Cyano-bridged Complexes;
氰基桥联配合物的合成、晶体结构和磁性质研究
Design, Synthesis of the Oxamido-Bridged Single Molecular Magnets (SMM) Complexes;
草酰胺桥联单分子磁体配合物的设计及合成
Magnetic Properties of Molecular Magnets Based on Multi-metal Complexes by Cyanides;
氰根桥联多金属配合物分子磁体的磁性研究
Magnetic Properties of Molecular Magnets Based on Metal Complexes by Oxalates
草酸根桥联金属配合物分子磁体的磁性研究
Cu(Ⅰ)-Synthesis and structure of polymer in nitrogen heterocyclics;
Cu(Ⅰ)-桥联双氮杂环配体配位聚合物的合成和结构
Study of Spectra and Crystal Structure of Bipyridine Bridging Cu(Ⅱ) Acetylacetonate Complex [μ-4, 4-bipy-Cu(acac)_2]
联吡啶桥联乙酰丙酮铜配合物的晶体结构和波谱研究
The structure, function and synthesis of those are discussed.
因此,本文对无机配体桥联化合物的结构、能及生物活性进行了讨论。
Synthesis and Crystal Structure of Two-Dimensional Network Copper(Ⅱ) Coordination Polymer Linked by Tartrate
酒石酸根桥联的二维网状铜(Ⅱ)配位聚合物的合成和晶体结构
Studies on Synthesis, Crystal Structure and Magnetic Properties of the Coordination Polymers with Aromatic Carboxylic Acid-bridge;
芳香羧酸桥联的配位聚合物的合成、晶体结构和磁性研究
Synthesis and Properties of Metal-Organic Frameworks with Halogen-Substituted Aromatic Carboxylate Ligands;
卤代芳香酸配体桥联的金属有机骨架材料的合成与性质的研究
Study on the Synthesis, Crystal Structure and Magnetic Properties of Cyano-bridged Transitional Metal Complexes
氰基桥联过渡金属配合物的合成、晶体结构与磁性研究
Synthesis,Characterization,Crystal Structure of Acetate Bridged Complex {[(tren)Zn(CH_3COO)Zn(tren)](BF_4)_3}
乙酸根桥联双核锌配合物的合成、表征及晶体结构
Synthesis and crystal structure of dinuclear cadmium(Ⅱ) complexes bridged by flexible dicarboxylate ligands
柔性二元羧酸桥联双核镉(Ⅱ)配合物的合成及晶体结构研究
Synthesis and Crystal Structural Study of Cl-bridged One-dimensional Cd(Ⅱ)Complex
氯桥联镉(Ⅱ)一维配位聚合物的合成及晶体结构研究
Syntheses and Self-Asembly of Rigid and Semirigid Five-Membered Heterocyclic Bridging Ligands and Symmetric Fulvene Ligands;
五元杂环桥联刚性、半刚性有机配体及富烯配体的合成及自组装研究