Two copper complexes, Cu2 μ-pz2HB(pz)32 (1) and CuB(pz)42 (2) (pz: pyrazole (C3H4N2)), with poly(pyrazolyl)borate and pyrazole as ligands, were synthesized successfully.
本文设计合成了两种以聚吡唑硼酸盐、吡唑为配体的铜配合物Cu2[μ-pz]2[HB(pz)3]2(1)和Cu[B(pz)4]2(2)(pz:吡唑(C3H4N2))。
In this paper, using the poly(pyrazolyl)borate as supporting ligand and the ammonia acid as the second ligand, a serises of oxovanadium complexes were synthesized s.
本文以聚吡唑硼酸盐为支撑配体,氨基酸为第二配体的系列钒氧配合物如下: 1、VO(pz)_4SO_4·H_2O 2、VO[PhCH_2CH(NH_2)COO)][HB(pz)_3 3、VO(3,5-Me_2pz)[HB(3,5-Me_2pz)_3] (CH_3COO) 4、K[(B(pz)_4)_2 (H_2O)_2(H_3O+)] 5、VO[B(pz)_4]_2测定了其晶体结构并对其进行了热分解动力学和量子化学计算的研究;运用红外、紫外、荧光光谱等手段进行了表征;对其配合物的合成进行了详细的讨论。
Poly(pyrazolyl)borate ligands have the ability to occupy three cis-coordination sites on the metal, the remaining coordinate sites can bind small molecules, such as amino acid, and so on, for controlling or modify properties of the complexes.
聚吡唑硼酸盐可以用来模拟多种金属蛋白(metalloproteins)中组氨酸-金属之间的作用,它可以像“老虎钳”一样卡住金属中心的三个顺式配位点,而留下另外的三个配位点为其它生物小分子与之配位或进行其他化学操作,并且也可作为各种生物酶模型的内在成分,模拟三个组氨酸氮配位的环境,这为设计和调控分子结构、改变分子特性和定向合成提供了前提。
Design、Synthesis and Characterization of Oxovanadium Complex Containing Poly (Pyrazolyl) Borate;
含有聚吡唑硼酸盐配体的钒氧配合物的设计、合成与表征
Design, Synthesis, Structure and Mimic Catalytic Activity of Oxovanadium Complexes with Poly(Pyrazolyl) Borate and Carboxylate Ligands
聚吡唑硼酸盐钒氧羧酸配合物的设计、合成、结构与仿生催化活性研究
Synthesis and characterization of poly(pyrazolyl)borate tantalum amides complexes and their reactivities toward oxygen
聚(吡唑)硼酸基-氨基钽化合物的合成、表征及和氧气的反应性
A Novel Mixed Ligands Sandwich Copper (Ⅱ) Complex with Hydrotris(pyrazolyl)borate and Bihydrobis(pyrazolyl)borate
新型三吡唑硼酸根和二吡唑硼酸根混合配体“三明治”型铜(Ⅱ)配合物
Synthesis of 3-amino-4-pyrazolecarboxamide hemisulfate
3-氨基吡唑-4-甲酰胺半硫酸盐的合成
Study on the synthesis of ionic liquid N-butylpyridine tetrafluoroborate
离子液体N-丁基吡啶四氟硼酸盐的合成研究
Determination of thiocyanate in urine with isonicotinic acid-pyrazolone spectrophotometric method
分光光度法测定尿中硫氰酸盐的异烟酸-吡唑酮
Quantum Chemical Study of Alkyl Imidazolium Tetrafluoroborate Ionic Liquids
烷基咪唑四氟硼酸盐离子液体的量子化学研究
A salt or an ester of boric acid.
硼酸盐一种硼酸盐或硼酸酯
Measurement of Solubilities of Toluene,Benzyl Alcohol,Benzaldehyde and Benzoic Acid in 1-Ethyl-3-Methylimidazolium Tetrafluoroborate
甲苯、苯甲醇(醛/酸)在1-乙基-3-甲基咪唑四氟硼酸盐中溶解度的测定
Water quality--Determination of thiocyanate-- isonicotinic acid pyrazolone spectrophotometry
GB/T13897-1992水质硫氰酸盐的测定异烟酸-吡唑啉酮分光光度法
Synthesis and Structure Chemistry of the Novel Polyborate Vanadate Materials;
新型多聚硼钒酸盐材料的合成和结构化学
Synthesis and Characterization of Ionic Liquids of the 1-isobutyl-3-methylimidazolium Tetrafluoroborate
离子液体1-异丁基-3-甲基咪唑四氟硼酸盐的合成与表征
Simulation Calculation of Structure Property of 1-ethyl-3-methylimidazolium Tetrafluoroborate Ionic Liquid
1-乙基-3-甲基咪唑四氟硼酸盐离子液体结构性质的模拟计算
Study on the microwave-assisted synthesis of ionic liquid 1-ethyl-3-methylimidazolium tetrafluoroborate
微波法合成离子液体1-乙基-3-甲基咪唑四氟硼酸盐的研究
STUDIES ON THE EXTRACTION OF NICKEL(Ⅱ)WITH 1-PHENYL-3-METHYL-4-BENZOYL-PYRAZOLONE-5 FROM ACETATE SOLUTION
1-苯基-3-甲基-4-苯甲酰基吡唑酮-5从醋酸盐中萃取镍的研究
Synthesis and characterization of novel ionic liquid pyrrolidine-based chiral triazole pyridinium
新型三氮唑吡啶盐负载的脯氨酸手性离子液体的合成和表征
Production : monomer boron, Danhuapeng, boron anhydride, without detectable; Hydrochloric acid, Yean, ammonia water.
生产：单体硼，氮化硼，硼酐，无水硼砂；盐酸，液氨，氨水。