Four SBUs(Secondary Building Units), containing controllable coordinated water molecules, and eleven coordinations were synthesized.
两个体系共合成了4个含可控制性配位水分子的SBUs(Secondary Building Units)和11个二次合成配合物,测定了这15个配合物的晶体结构并进行了元素分析、IR、和单晶X-射线衍射等结构表征,初步分析了这15个配合物的磁学性质,很好地解释了结构-磁性间的关系。
Synthesis,crystal structure and spectral analysis of 1D double-chain Mn(Ⅱ) coordination supramolecule bridged by o-phthalic acid;
邻苯二甲酸桥联的一维双链锰配位超分子的合成、晶体结构及光谱分析
Three Mn(Ⅱ) coordination supramolecules Mn(2,5-dcp)2(H2O)2 (1),Mn(INA)2(H2O)4 (2) and Mn(phen)2Cl2 (3) were synthesized by hydrothermal method (2,5-dcp=pyridine-2,5-dicarboxylic acid,INA= iso-nicotinic acid,phen=1,10-phenanthroline).
采用水热合成方法得到了三种Mn(Ⅱ)配位超分子:Mn(2,5-dcp)2(H2O)2(1),Mn(INA)2(H2O)4(2)和Mn(phen)2Cl2(3)(2,5-dcp=pyridine-2,5-dicarboxylic acid,INA=iso-nicotinic acid,phen=1,10-phenanthroline)。
The coordination polymer ｛Zn 3(Ac) 4(4,4′ bpy) 3[N(CN) 2] 2} n is prepared and characterized by X\|ray diffraction.
合成了配位高分子 {Zn3(Ac) 4 (4,4′ bpy) 3[N(CN) 2 ]2 } n,并用X射线衍射表征了其结构 ,结构包含一个独特的三腿梯子。
Recently the employment of pre-designed and functional bi- or polynuclear units as building blocks to construct coordination polymers, especially low-dimensional polymers, is an attractive road to functional materials, in which way the reaction condition is quite mild and the control of product is easy to achieve, and also synthetic materials may posses.
近些年来,利用双核或多核金属配合物作为“结构单元”构建配位高分子,特别是低维配位高分子,已成为一种非常引人注目的制备功能材料的途径。
In this article, the importance of the temperature dependence of molecule coordination numbers in establishing local composition models has been studied.
本文通过统计力学理论对分子配位数与温度之间的函数关系在建立局部组成模型中的重要性进行探讨,发现早期局部组成模型中(诸如Wilson、NPTL方程等)分子配位数作为恒定常数的假设不太合理,这一不合理假设导致了这些模型不能满足第二维里系数对组成的二次依赖性等理论缺陷,从而限制了这些模型对低密度流体混合物的应用。
Syntheses, Structures and Properties of Coordination Polymers and Coordination Supermolecule with Azacyclic Ligands;
氮杂环配位聚合物及配位超分子的合成、结构与性质
Assembly, Structures and Properties of Complexes Constructed from Transition Metal with Unsaturated Carboxylates;
不饱和酸与过渡金属配位超分子化合物的组装、结构与性质研究
Synthesis, Structure and Spectroscopic Properties of Copper(I)/Gold(I) Supramolecular Complexes Containing Phosphine, Nitrogen Heterocycle Ligands;
含膦、氮杂环的Cu～I/Au～I配位超分子的合成、表征及其光谱性质研究
Synthesis,crystal structure and Photo-physical property of a series of Co~(n+)(n=2,3) coordination supramolecules
系列Co~(n+)(n=2,3)配位超分子的晶体结构及光物理性质研究
Preparation and Light-Induced Surface Electron Behavior of Ni(Ⅱ) Based on Aromatic Polycarboxyl Acids
以芳香族多羧酸为配体的Ni(Ⅱ)配位超分子的研制及光诱导下的表面电子行为
Construction of Supramolecular Networks Based on Coordination and Hydrogen Bonds;
基于配位键和氢键的超分子网络结构
Transition Metal Superamolecular Coordinate Polymer Construction and Structural Research;
过渡金属超分子配位聚合物的构建与结构研究
Coordination and Supramolecule Study Based on 4,4',6,6'-Tetramethyl-2,2'-Bipyrimidine
4，4’，6，6’-四甲基-2，2’-联嘧啶的配位及超分子研究
Synthesis and Structures of a Few Transition Metals Coordination Polymers Constructed by Supramolecular Self-assembly;
几个含氮、氧多齿配体配位聚合物的超分子组装及结构表征
Analysis of Oleanane and Ursane Pentacyclic Triterpenoids by Supramolecular Coordination Chromatography;
乌苏烷和齐墩果烷型五环三萜的超分子配位色谱分析
Study on the Supramolecular Character of Pyridine Carboxamide Complex and the Bioactivity of Multi(5-florouracil);
吡啶酰胺的超分子配位特性与多尿嘧啶生物活性研究
Synthesis and Characterization of the Supermolecule and Coordination Polymers Constructed Through Metal-Bipyridine Dicarboxylic Acid;
金属—联吡啶二甲酸超分子化合物及配位聚合物的合成与表征
Preparation and STM Investigation of Supramolecular SAMs Directed by Lateral Hydrogen Bonds and Metal-organic Coordination Bonds;
氢键及配位键作用下表面超分子自组装膜的制备及STM表征
Synthesis, Crystal Structure, Supramolecular Assembly and DNA Binding Studies of Complexes Containing C, N, and O Coordination Atoms;
含C、N、O配位原子配合物的合成、结构、超分子组装及其与DNA相互作用研究
Synthesis, Structures and Properties of Novel Supramolecular Coordination Polymers Generated from 5-Nitroisophthlate Ligand;
5-硝基间苯二甲酸桥联配体构筑的超分子配位聚合物的合成、结构及性能研究
Synthesis and Properties of Bipyrazolate-Linked Metallo-Supramolecular Microcycles and One-Dimensional Coordination Polymer;
双吡唑配体金属基超分子大环和一维螺旋配位聚合物的合成与性质研究
Research on Supramolecular Complexes with Flexible Open-chain Schiff Base Ligands;
柔性开链席夫碱配体金属超分子配合物研究
Studies on the Supramolecular Rare Earth Complexes with Amide-type Podands;
酰胺型多足配体稀土超分子配合物的研究